In quantum physics, the Heisenberg uncertainty principle states that certain pairs of physical properties, like position and momentum, cannot both be known to arbitrary precision. That is, the more precisely one property is known, the less precisely the other can be known. It is impossible to measure simultaneously both position and velocity of a microscopic particle with any degree of accuracy or certainty. This is not only a statement about the limitations of a researcher's ability to measure particular quantities of a system, following the tenets of logical positivism, it is a statement about the nature of the system itself.
In quantum mechanics, a particle is described by a wave. The position is where the wave is concentrated and the momentum is the wavelength. The position is uncertain to the degree that the wave is spread out, and the momentum is uncertain to the degree that the wavelength is ill-defined.
The only kind of wave with a definite position is concentrated at one point, and such a wave has an indefinite wavelength. Conversely, the only kind of wave with a definite wavelength is an infinite regular periodic oscillation over all space, which has no definite position. So in quantum mechanics, there are no states that describe a particle with both a definite position and a definite momentum. The more precise the position, the less precise the momentum.
The uncertainty principle can be restated in terms of measurements, which involves collapse of the wavefunction. When the position is measured, the wavefunction collapses to a narrow bump near the measured value, and the momentum wavefunction becomes spread out. The particle's momentum is left uncertain by an amount inversely proportional to the accuracy of the position measurement. The amount of left-over uncertainty can never be reduced below the limit set by the uncertainty principle, no matter what the measurement process.
This means that the uncertainty principle is related to the observer effect, with which it is often conflated. The uncertainty principle sets a lower limit to how small the momentum disturbance in an accurate position experiment can be, and vice versa for momentum experiments.
A mathematical statement of the principle is that every quantum state has the property that the root-mean-square (RMS) deviation of the position from its mean (the standard deviation of the X-distribution):
times the RMS deviation of the momentum from its mean (the standard deviation of P):
can never be smaller than a fixed fraction of Planck's constant:
Any measurement of the position with accuracy collapses the quantum state making the standard deviation of the momentum larger than .
Contents[hide]
1 Historical introduction
2 Uncertainty principle and observer effect
2.1 Heisenberg's microscope
3 Critical reactions
3.1 Einstein's slit
3.2 Einstein's box
3.3 EPR measurements
3.4 Popper's criticism
4 Refinements
4.1 Entropic uncertainty principle
5 Derivations
5.1 Physical interpretation
5.2 Matrix mechanics
5.3 Wave mechanics
5.4 Symplectic geometry
6 Robertson–Schrödinger relation
6.1 Other uncertainty principles
7 Energy-time uncertainty principle
8 Uncertainty theorems in harmonic analysis
8.1 Benedicks's theorem
8.2 Hardy's uncertainty principle
9 Popular culture
10 See also
11 Notes
12 References
13 External links
//
[edit] Historical introduction
Main article: Introduction to quantum mechanics
Werner Heisenberg formulated the uncertainty principle in Niels Bohr's institute at Copenhagen, while working on the mathematical foundations of quantum mechanics.
In 1925, following pioneering work with Hendrik Kramers, Heisenberg developed matrix mechanics, which replaced the ad-hoc old quantum theory with modern quantum mechanics. The central assumption was that the classical motion was not precise at the quantum level, and electrons in an atom did not travel on sharply defined orbits. Rather, the motion was smeared out in a strange way: the time Fourier transform only involving those frequencies that could be seen in quantum jumps.
Heisenberg's paper did not admit any unobservable quantities like the exact position of the electron in an orbit at any time; he only allowed the theorist to talk about the Fourier components of the motion. Since the Fourier components were not defined at the classical frequencies, they could not be used to construct an exact trajectory, so that the formalism could not answer certain overly precise questions about where the electron was or how fast it was going.
The most striking property of Heisenberg's infinite matrices for the position and momentum is that they do not commute. Heisenberg's canonical commutation relation tells you by how much:
and this result did not have a clear physical interpretation in the beginning.
In March 1926, working in Bohr's institute, Heisenberg realized that the non-commutativity implies the uncertainty principle. This was a clear physical interpretation for the non-commutativity, and it laid the foundation for what became known as the Copenhagen interpretation of quantum mechanics. Heisenberg showed that the commutation relations implies an uncertainty, or in Bohr's language a complementarity.[1] Any two variables that do not commute cannot be measured simultaneously—the more precisely one is known, the less precisely the other can be known.
One way to understand the complementarity between position and momentum is by wave-particle duality. If a particle described by a plane wave passes through a narrow slit in a wall like a water-wave passing through a narrow channel, the particle diffracts and its wave comes out in a range of angles. The narrower the slit, the wider the diffracted wave and the greater the uncertainty in momentum afterwards. The laws of diffraction require that the spread in angle Δθ is about λ / d, where d is the slit width and λ is the wavelength. From the de Broglie relation, the size of the slit and the range in momentum of the diffracted wave are related by Heisenberg's rule:
In his celebrated paper (1927), Heisenberg established this expression as the minimum amount of unavoidable momentum disturbance caused by any position measurement[2], but he did not give a precise definition for the uncertainties Δx and Δp. Instead, he gave some plausible estimates in each case separately. In his Chicago lecture[3] he refined his principle:
(1)
But it was Kennard[4] in 1927 who first proved the modern inequality:
(2)
where , and σx, σp are the standard deviations of position and momentum. Heisenberg himself only proved relation (2) for the special case of Gaussian states.[3].
[edit] Uncertainty principle and observer effect
The uncertainty principle is often stated this way:
The measurement of position necessarily disturbs a particle's momentum, and vice versa
This makes the uncertainty principle a kind of observer effect.
This explanation is not incorrect, and was used by both Heisenberg and Bohr. But they were working within the philosophical framework of logical positivism. In this way of looking at the world, the true nature of a physical system, inasmuch as it exists, is defined by the answers to the best-possible measurements which can be made in principle. So when they made arguments about unavoidable disturbances in any conceivable measurement, it was obvious to them that this uncertainty was a property of the system, not of the devices.
Today, logical positivism has become unfashionable in many cases, so the explanation of the uncertainty principle in terms of observer effect can be misleading. For one, this explanation makes it seem to the non positivist that the disturbances are not a property of the particle, but a property of the measurement process— the particle secretly does have a definite position and a definite momentum, but the experimental devices we have are not good enough to find out what these are. This interpretation is not compatible with standard quantum mechanics. In quantum mechanics, states which have both definite position and definite momentum at the same time just don't exist.
This explanation is misleading in another way, because sometimes it is a failure to measure the particle that produces the disturbance. For example, if a perfect photographic film contains a small hole, and an incident photon is not observed, then its momentum becomes uncertain by a large amount. By not observing the photon, we discover indirectly that it went through the hole, revealing the photon's position.
The third way in which the explanation can be misleading is due to the nonlocal nature of a quantum state. Sometimes, two particles can be entangled, and then a distant measurement can be performed on one of the two. This measurement should not disturb the other particle in any classical sense, but it can sometimes reveal information about the distant particle. This restricts the possible values of position or momentum in strange ways.
Unlike the other examples, a distant measurement will never cause the overall distribution of either position or momentum to change. The distribution only changes if the results of the distant measurement are known. A secret distant measurement has no effect whatsoever on a particle's position or momentum distribution. But the distant measurement of momentum for instance will still reveal new information, which causes the total wavefunction to collapse. This will restrict the distribution of position and momentum, once that classical information has been revealed and transmitted.
For example If two photons are emitted in opposite directions from the decay of positronium, the momenta of the two photons are opposite. By measuring the momentum of one particle, the momentum of the other is determined, making its momentum distribution sharper, and leaving the position just as indeterminate. But unlike a local measurement, this process can never produce more position uncertainty than what was already there. It is only possible is to restrict the uncertainties in different ways, with different statistical properties, depending on what property of the distant particle you choose to measure. By restricting the uncertainty in p to be very small by a distant measurement, the remaining uncertainty in x stays large. (This example was actually the basis of Albert Einstein's important suggestion of the EPR paradox in 1935.)
This queer mechanism of quantum mechanics is the basis of quantum cryptography, where the measurement of a value on one of two entangled particles at one location forces, via the uncertainty principle, a property of a distant particle to become indeterminate and hence unmeasurable.
But Heisenberg did not focus on the mathematics of quantum mechanics, he was primarily concerned with establishing that the uncertainty is actually a property of the world — that it is in fact physically impossible to measure the position and momentum of a particle to a precision better than that allowed by quantum mechanics. To do this, he used physical arguments based on the existence of quanta, but not the full quantum mechanical formalism.
This was a surprising prediction of quantum mechanics, and not yet accepted. Many people would have considered it a flaw that there are no states of definite position and momentum. Heisenberg was trying to show this was not a bug, but a feature—a deep, surprising aspect of the universe. To do this, he could not just use the mathematical formalism, because it was the mathematical formalism itself that he was trying to justify.
[edit] Heisenberg's microscope
Heisenberg's gamma-ray microscope for locating an electron (shown in blue). The incoming gamma ray (shown in green) is scattered by the electron up into the microscope's aperture angle θ. The scattered gamma-ray is shown in red. Classical optics shows that the electron position can be resolved only up to an uncertainty Δx that depends on θ and the wavelength λ of the incoming light.
Main article: Heisenberg's microscope
One way in which Heisenberg originally argued for the uncertainty principle is by using an imaginary microscope as a measuring device.[3] He imagines an experimenter trying to measure the position and momentum of an electron by shooting a photon at it.
If the photon has a short wavelength, and therefore a large momentum, the position can be measured accurately. But the photon scatters in a random direction, transferring a large and uncertain amount of momentum to the electron. If the photon has a long wavelength and low momentum, the collision doesn't disturb the electron's momentum very much, but the scattering will reveal its position only vaguely.
If a large aperture is used for the microscope, the electron's location can be well resolved (see Rayleigh criterion); but by the principle of conservation of momentum, the transverse momentum of the incoming photon and hence the new momentum of the electron resolves poorly. If a small aperture is used, the accuracy of the two resolutions is the other way around.
The trade-offs imply that no matter what photon wavelength and aperture size are used, the product of the uncertainty in measured position and measured momentum is greater than or equal to a lower bound, which is up to a small numerical factor equal to Planck's constant.[5] Heisenberg did not care to formulate the uncertainty principle as an exact bound, and preferred to use it as a heuristic quantitative statement, correct up to small numerical factors.
[edit] Critical reactions
Main article: Einstein-Bohr debates
The Copenhagen interpretation of quantum mechanics and Heisenberg's Uncertainty Principle were in fact seen as twin targets by detractors who believed in an underlying determinism and realism. Within the Copenhagen interpretation of quantum mechanics, there is no fundamental reality the quantum state describes, just a prescription for calculating experimental results. There is no way to say what the state of a system fundamentally is, only what the result of observations might be.
Albert Einstein believed that randomness is a reflection of our ignorance of some fundamental property of reality, while Niels Bohr believed that the probability distributions are fundamental and irreducible, and depend on which measurements we choose to perform. Einstein and Bohr debated the uncertainty principle for many years.
[edit] Einstein's slit
The first of Einstein's thought experiments challenging the uncertainty principle went as follows:
Consider a particle passing through a slit of width d. The slit introduces an uncertainty in momentum of approximately h/d because the particle passes through the wall. But let us determine the momentum of the particle by measuring the recoil of the wall. In doing so, we find the momentum of the particle to arbitrary accuracy by conservation of momentum.
Bohr's response was that the wall is quantum mechanical as well, and that to measure the recoil to accuracy ΔP the momentum of the wall must be known to this accuracy before the particle passes through. This introduces an uncertainty in the position of the wall and therefore the position of the slit equal to h / ΔP, and if the wall's momentum is known precisely enough to measure the recoil, the slit's position is uncertain enough to disallow a position measurement.
A similar analysis with particles diffracting through multiple slits is given by Richard Feynman[6].
[edit] Einstein's box
Another of Einstein's thought experiments was designed to challenge the time/energy uncertainty principle. It is very similar to the slit experiment in space, except here the narrow window the particle passes through is in time:
Consider a box filled with light. The box has a shutter that a clock opens and quickly closes at a precise time, and some of the light escapes. We can set the clock so that the time that the energy escapes is known. To measure the amount of energy that leaves, Einstein proposed weighing the box just after the emission. The missing energy lessens the weight of the box. If the box is mounted on a scale, it is naively possible to adjust the parameters so that the uncertainty principle is violated.
Bohr spent a day considering this setup, but eventually realized that if the energy of the box is precisely known, the time the shutter opens at is uncertain. If the case, scale, and box are in a gravitational field then, in some cases, it is the uncertainty of the position of the clock in the gravitational field that alters the ticking rate. This can introduce the right amount of uncertainty. This was ironic, because it was Einstein himself who first discovered gravity's effect on clocks.
[edit] EPR measurements
Bohr was compelled to modify his understanding of the uncertainty principle after another thought experiment by Einstein. In 1935, Einstein, Podolski and Rosen (see EPR paradox) published an analysis of widely separated entangled particles. Measuring one particle, Einstein realized, would alter the probability distribution of the other, yet here the other particle could not possibly be disturbed. This example led Bohr to revise his understanding of the principle, concluding that the uncertainty was not caused by a direct interaction.[7]
But Einstein came to much more far-reaching conclusions from the same thought experiment. He believed as "natural basic assumption" that a complete description of reality would have to predict the results of experiments from "locally changing deterministic quantities", and therefore would have to include more information than the maximum possible allowed by the uncertainty principle.
In 1964 John Bell showed that this assumption can be falsified, since it would imply a certain inequality between the probabilities of different experiments. Experimental results confirm the predictions of quantum mechanics, ruling out Einstein's basic assumption that led him to the suggestion of his hidden variables. (Ironically this is one of the best examples for Karl Popper's philosophy of invalidation of a theory by falsification-experiments; i.e. here Einstein's "basic assumption" became falsified by experiments based on Bells inequalities; for the objections of Karl Popper against the Heisenberg inequality itself, see below.)
While it is possible to assume that quantum mechanical predictions are due to nonlocal hidden variables, and in fact David Bohm invented such a formulation, this is not a satisfactory resolution for the vast majority of physicists. The question of whether a random outcome is predetermined by a nonlocal theory can be philosophical, and potentially intractable. If the hidden variables are not constrained, they could just be a list of random digits that are used to produce the measurement outcomes. To make it sensible, the assumption of nonlocal hidden variables is sometimes augmented by a second assumption — that the size of the observable universe puts a limit on the computations that these variables can do. A nonlocal theory of this sort predicts that a quantum computer encounters fundamental obstacles when it tries to factor numbers of approximately 10,000 digits or more; an achievable task in quantum mechanics[8].
[edit] Popper's criticism
Karl Popper criticized Heisenberg's form of the uncertainty principle, that a measurement of position disturbs the momentum, based on the following observation: if a particle with definite momentum passes through a narrow slit, the diffracted wave has some amplitude to go in the original direction of motion. If the momentum of the particle is measured after it goes through the slit, there is always some probability, however small, that the momentum will be the same as it was before.
Popper thinks of these rare events as falsifications of the uncertainty principle in Heisenberg's original formulation. To preserve the principle, he concludes that Heisenberg's relation does not apply to individual particles or measurements, but only to many identically prepared particles, called ensembles. Popper's criticism applies to nearly all probabilistic theories, since a probabilistic statement requires many measurements to either verify or falsify.
Popper's criticism does not trouble physicists who subscribe to Copenhagen interpretation. Popper's presumption is that the measurement is revealing some preexisting information about the particle, the momentum, which the particle already possesses. According to Copenhagen interpretation the quantum mechanical description the wavefunction is not a reflection of ignorance about the values of some more fundamental quantities, it is the complete description of the state of the particle. In this philosophical view, Popper's example is not a falsification, since after the particle diffracts through the slit and before the momentum is measured, the wavefunction is changed so that the momentum is still as uncertain as the principle demands.
[edit] Refinements
[edit] Entropic uncertainty principle
Main article: Hirschman uncertainty
While formulating the many-worlds interpretation of quantum mechanics in 1957, Hugh Everett III discovered a much stronger formulation of the uncertainty principle[9]. In the inequality of standard deviations, some states, like the wavefunction
have a large standard deviation of position, but are actually a superposition of a small number of very narrow bumps. In this case, the momentum uncertainty is much larger than the standard deviation inequality would suggest. A better inequality uses the Shannon information content of the distribution, a measure of the number of bits learned when a random variable described by a probability distribution has a certain value.
The interpretation of I is that the number of bits of information an observer acquires when the value of x is given to accuracy ε is equal to Ix + log2(ε). The second part is just the number of bits past the decimal point, the first part is a logarithmic measure of the width of the distribution. For a uniform distribution of width Δx the information content is log2Δx. This quantity can be negative, which means that the distribution is narrower than one unit, so that learning the first few bits past the decimal point gives no information since they are not uncertain.
Taking the logarithm of Heisenberg's formulation of uncertainty in natural units.
but the lower bound is not precise.
Everett (and Hirschman[10]) conjectured that for all quantum states:
This was proven by Beckner in 1975[11].
[edit] Derivations
When linear operators A and B act on a function ψ(x), they don't always commute. A clear example is when operator B multiplies by x, while operator A takes the derivative with respect to x. Then
which in operator language means that
This example is important, because it is very close to the canonical commutation relation of quantum mechanics. There, the position operator multiplies the value of the wavefunction by x, while the corresponding momentum operator differentiates and multiplies by , so that:
It is the nonzero commutator that implies the uncertainty.
For any two operators A and B:
which is a statement of the Cauchy-Schwarz inequality for the inner product of the two vectors and . The expectation value of the product AB is greater than the magnitude of its imaginary part:
and putting the two inequalities together for Hermitian operators gives a form of the Robertson-Schrödinger relation:
and the uncertainty principle is a special case.
[edit] Physical interpretation
The inequality above acquires its physical interpretation:
where
is the mean of observable X in the state ψ and
is the standard deviation of observable X in the system state ψ.
By substituting for A and for B in the general operator norm inequality, since the imaginary part of the product, the commutator, is unaffected by the shift:
The big side of the inequality is the product of the norms of and , which in quantum mechanics are the standard deviations of A and B. The small side is the norm of the commutator, which for the position and momentum is just .
[edit] Matrix mechanics
In matrix mechanics, the commutator of the matrices X and P is always nonzero, it is a constant multiple of the identity matrix. This means that it is impossible for a state to have a definite values x for X and p for P, since then XP would be equal to the number xp and would equal PX.
The commutator of two matrices is unchanged when they are shifted by a constant multiple of the identity — for any two real numbers x and p
Given any quantum state ψ, define the number x
to be the expected value of the position, and
to be the expected value of the momentum. The quantities and are only nonzero to the extent that the position and momentum are uncertain, to the extent that the state contains some values of X and P that deviate from the mean. The expected value of the commutator
can only be nonzero if the deviations in X in the state times the deviations in P are large enough.
The size of the typical matrix elements can be estimated by summing the squares over the energy states :
and this is equal to the square of the deviation, matrix elements have a size approximately given by the deviation.
So, to produce the canonical commutation relations, the product of the deviations in any state has to be about .
This heuristic estimate can be made into a precise inequality using the Cauchy-Schwartz inequality, exactly as before. The inner product of the two vectors in parentheses:
is bounded above by the product of the lengths of each vector:
so, rigorously, for any state:
the real part of a matrix M is , so that the real part of the product of two Hermitian matrices is:
while the imaginary part is
The magnitude of is bigger than the magnitude of its imaginary part, which is the expected value of the imaginary part of the matrix:
Note that the uncertainty product is for the same reason bounded below by the expected value of the anticommutator, which adds a term to the uncertainty relation. The extra term is not as useful for the uncertainty of position and momentum, because it has zero expected value in a gaussian wavepacket, like the ground state of a harmonic oscillator. The anticommutator term is useful for bounding the uncertainty of spin operators though.
[edit] Wave mechanics
See also: Fourier uncertainty principle
In Schrödinger's wave mechanics, the quantum mechanical wavefunction contains information about both the position and the momentum of the particle. The position of the particle is where the wave is concentrated, while the momentum is the typical wavelength.
The wavelength of a localized wave cannot be determined very well. If the wave extends over a region of size L and the wavelength is approximately λ, the number of cycles in the region is approximately L / λ. The inverse of the wavelength can be changed by about 1 / L without changing the number of cycles in the region by a full unit, and this is approximately the uncertainty in the inverse of the wavelength,
This is an exact counterpart to a well known result in signal processing — the shorter a pulse in time, the less well defined the frequency. The width of a pulse in frequency space is inversely proportional to the width in time. It is a fundamental result in Fourier analysis, the narrower the peak of a function, the broader the Fourier transform.
Multiplying by h, and identifying ΔP = hΔ(1 / λ), and identifying ΔX = L.
The uncertainty Principle can be seen as a theorem in Fourier analysis: the standard deviation of the squared absolute value of a function, times the standard deviation of the squared absolute value of its Fourier transform, is at least 1/(16π2) (Folland and Sitaram, Theorem 1.1).
An instructive example is the (unnormalized) gaussian wave-function
The expectation value of X is zero by symmetry, and so the variance is found by averaging X2 over all positions with the weight ψ(x)2, careful to divide by the normalization factor.
The Fourier transform of the Gaussian is the wavefunction in k space, where k is the wavenumber and is related to the momentum by DeBroglie's relation :
The last integral does not depend on p, because there is a continuous change of variables which removes the dependence, and this deformation of the integration path in the complex plane does not pass through any singularities. So up to normalization, the answer is again a Gaussian.
The width of the distribution in k is found in the same way as before, and the answer just flips A to 1/A.
so that for this example
which shows that the uncertainty relation inequality is tight. There are wavefunctions that saturate the bound.
[edit] Symplectic geometry
This section requires expansion.
In mathematical terms, conjugate variables forms part of a symplectic basis, and the uncertainty principle corresponds to the symplectic form.
[edit] Robertson–Schrödinger relation
Given any two Hermitian operators A and B, and a system in the state ψ, there are probability distributions for the value of a measurement of A and B, with standard deviations ΔψA and ΔψB. Then
where [A,B] = AB - BA is the commutator of A and B, {A,B}= AB+BA is the anticommutator, and is the expectation value. This inequality is called the Robertson-Schrödinger relation, and includes the Heisenberg uncertainty principle as a special case. The inequality with the commutator term only was developed in 1930 by Howard Percy Robertson, and Erwin Schrödinger added the anticommutator term a little later.
[edit] Other uncertainty principles
The Robertson Schrödinger relation gives the uncertainty relation for any two observables that do not commute:
There is an uncertainty relation between the position and momentum of an object:
between the energy and position of a particle in a one-dimensional potential V(x):
between angular position and angular momentum of an object with small angular uncertainty:
between two orthogonal components of the total angular momentum operator of an object:
where i, j, k are distinct and Ji denotes angular momentum along the xi axis.
between the number of electrons in a superconductor and the phase of its Ginzburg-Landau order parameter[12][13]
[edit] Energy-time uncertainty principle
One well-known uncertainty relation is not an obvious consequence of the Robertson-Schrödinger relation: the energy-time uncertainty principle.
Since energy bears the same relation to time as momentum does to space in special relativity, it was clear to many early founders, Niels Bohr among them, that the following relation holds:
but it was not obvious what Δt is, because the time at which the particle has a given state is not an operator belonging to the particle, it is a parameter describing the evolution of the system. As Lev Landau once joked "To violate the time-energy uncertainty relation all I have to do is measure the energy very precisely and then look at my watch!"
Nevertheless, Einstein and Bohr understood the heuristic meaning of the principle. A state that only exists for a short time cannot have a definite energy. To have a definite energy, the frequency of the state must accurately be defined, and this requires the state to hang around for many cycles, the reciprocal of the required accuracy.
For example, in spectroscopy, excited states have a finite lifetime. By the time-energy uncertainty principle, they do not have a definite energy, and each time they decay the energy they release is slightly different. The average energy of the outgoing photon has a peak at the theoretical energy of the state, but the distribution has a finite width called the natural linewidth. Fast-decaying states have a broad linewidth, while slow decaying states have a narrow linewidth.
The broad linewidth of fast decaying states makes it difficult to accurately measure the energy of the state, and researchers have even used microwave cavities to slow down the decay-rate, to get sharper peaks[14]. The same linewidth effect also makes it difficult to measure the rest mass of fast decaying particles in particle physics. The faster the particle decays, the less certain is its mass.
One false formulation of the energy-time uncertainty principle says that measuring the energy of a quantum system to an accuracy ΔE requires a time interval Δt > h / ΔE. This formulation is similar to the one alluded to in Landau's joke, and was explicitly invalidated by Y. Aharonov and D. Bohm in 1961. The time Δt in the uncertainty relation is the time during which the system exists unperturbed, not the time during which the experimental equipment is turned on.
In 1936, Dirac offered a precise definition and derivation of the time-energy uncertainty relation, in a relativistic quantum theory of "events". In this formulation, particles followed a trajectory in space time, and each particle's trajectory was parametrized independently by a different proper time. The many-times formulation of quantum mechanics is mathematically equivalent to the standard formulations, but it was in a form more suited for relativistic generalization. It was the inspiration for Shin-Ichiro Tomonaga's covariant perturbation theory for quantum electrodynamics.
But a better-known, more widely-used formulation of the time-energy uncertainty principle was given only in 1945 by L. I. Mandelshtam and I. E. Tamm, as follows.[15] For a quantum system in a non-stationary state and an observable B represented by a self-adjoint operator , the following formula holds:
where ΔψE is the standard deviation of the energy operator in the state , ΔψB stands for the standard deviation of the operator and is the expectation value of in that state. Although, the second factor in the left-hand side has dimension of time, it is different from the time parameter that enters Schrödinger equation. It is a lifetime of the state with respect to the observable B. In other words, this is the time after which the expectation value changes appreciably.
[edit] Uncertainty theorems in harmonic analysis
In the context of harmonic analysis, the uncertainty principle implies that one cannot at the same time localize the value of a function and its Fourier transform; to wit, the following inequality holds
Other purely mathematical formulations of uncertainty exist between a function ƒ and its Fourier transform. A variety of such results can be found in (Havin & Jöricke 1994) or (Folland & Sitaram 1997); for a short survey, see (Sitaram 2001).
[edit] Benedicks's theorem
Benedicks's theorem (Benedicks 1985) intuitively says that the set of points where ƒ is non-zero and the set of points where is nonzero cannot both be small. Specifically, it is impossible for a function ƒ in L2(R) and its Fourier transform to both be supported on sets of finite Lebesgue measure. In signal processing, this result is well-known: a function cannot be both time limited and band limited.
[edit] Hardy's uncertainty principle
The mathematician G. H. Hardy (Hardy 1933) formulated the following uncertainty principle: it is not possible for ƒ and to both be "very rapidly decreasing." Specifically, if ƒ is in L2(R), then one has
unless ƒ = 0. Note that this result is sharp, since the Fourier transform of ƒ0(x) = e−πx2 is equal to e−πξ2: if e2π xξ is replaced in the integral above by ea xξ , for any a <>
In quantum mechanics, a particle is described by a wave. The position is where the wave is concentrated and the momentum is the wavelength. The position is uncertain to the degree that the wave is spread out, and the momentum is uncertain to the degree that the wavelength is ill-defined.
The only kind of wave with a definite position is concentrated at one point, and such a wave has an indefinite wavelength. Conversely, the only kind of wave with a definite wavelength is an infinite regular periodic oscillation over all space, which has no definite position. So in quantum mechanics, there are no states that describe a particle with both a definite position and a definite momentum. The more precise the position, the less precise the momentum.
The uncertainty principle can be restated in terms of measurements, which involves collapse of the wavefunction. When the position is measured, the wavefunction collapses to a narrow bump near the measured value, and the momentum wavefunction becomes spread out. The particle's momentum is left uncertain by an amount inversely proportional to the accuracy of the position measurement. The amount of left-over uncertainty can never be reduced below the limit set by the uncertainty principle, no matter what the measurement process.
This means that the uncertainty principle is related to the observer effect, with which it is often conflated. The uncertainty principle sets a lower limit to how small the momentum disturbance in an accurate position experiment can be, and vice versa for momentum experiments.
A mathematical statement of the principle is that every quantum state has the property that the root-mean-square (RMS) deviation of the position from its mean (the standard deviation of the X-distribution):
times the RMS deviation of the momentum from its mean (the standard deviation of P):
can never be smaller than a fixed fraction of Planck's constant:
Any measurement of the position with accuracy collapses the quantum state making the standard deviation of the momentum larger than .
Contents[hide]
1 Historical introduction
2 Uncertainty principle and observer effect
2.1 Heisenberg's microscope
3 Critical reactions
3.1 Einstein's slit
3.2 Einstein's box
3.3 EPR measurements
3.4 Popper's criticism
4 Refinements
4.1 Entropic uncertainty principle
5 Derivations
5.1 Physical interpretation
5.2 Matrix mechanics
5.3 Wave mechanics
5.4 Symplectic geometry
6 Robertson–Schrödinger relation
6.1 Other uncertainty principles
7 Energy-time uncertainty principle
8 Uncertainty theorems in harmonic analysis
8.1 Benedicks's theorem
8.2 Hardy's uncertainty principle
9 Popular culture
10 See also
11 Notes
12 References
13 External links
//
[edit] Historical introduction
Main article: Introduction to quantum mechanics
Werner Heisenberg formulated the uncertainty principle in Niels Bohr's institute at Copenhagen, while working on the mathematical foundations of quantum mechanics.
In 1925, following pioneering work with Hendrik Kramers, Heisenberg developed matrix mechanics, which replaced the ad-hoc old quantum theory with modern quantum mechanics. The central assumption was that the classical motion was not precise at the quantum level, and electrons in an atom did not travel on sharply defined orbits. Rather, the motion was smeared out in a strange way: the time Fourier transform only involving those frequencies that could be seen in quantum jumps.
Heisenberg's paper did not admit any unobservable quantities like the exact position of the electron in an orbit at any time; he only allowed the theorist to talk about the Fourier components of the motion. Since the Fourier components were not defined at the classical frequencies, they could not be used to construct an exact trajectory, so that the formalism could not answer certain overly precise questions about where the electron was or how fast it was going.
The most striking property of Heisenberg's infinite matrices for the position and momentum is that they do not commute. Heisenberg's canonical commutation relation tells you by how much:
and this result did not have a clear physical interpretation in the beginning.
In March 1926, working in Bohr's institute, Heisenberg realized that the non-commutativity implies the uncertainty principle. This was a clear physical interpretation for the non-commutativity, and it laid the foundation for what became known as the Copenhagen interpretation of quantum mechanics. Heisenberg showed that the commutation relations implies an uncertainty, or in Bohr's language a complementarity.[1] Any two variables that do not commute cannot be measured simultaneously—the more precisely one is known, the less precisely the other can be known.
One way to understand the complementarity between position and momentum is by wave-particle duality. If a particle described by a plane wave passes through a narrow slit in a wall like a water-wave passing through a narrow channel, the particle diffracts and its wave comes out in a range of angles. The narrower the slit, the wider the diffracted wave and the greater the uncertainty in momentum afterwards. The laws of diffraction require that the spread in angle Δθ is about λ / d, where d is the slit width and λ is the wavelength. From the de Broglie relation, the size of the slit and the range in momentum of the diffracted wave are related by Heisenberg's rule:
In his celebrated paper (1927), Heisenberg established this expression as the minimum amount of unavoidable momentum disturbance caused by any position measurement[2], but he did not give a precise definition for the uncertainties Δx and Δp. Instead, he gave some plausible estimates in each case separately. In his Chicago lecture[3] he refined his principle:
(1)
But it was Kennard[4] in 1927 who first proved the modern inequality:
(2)
where , and σx, σp are the standard deviations of position and momentum. Heisenberg himself only proved relation (2) for the special case of Gaussian states.[3].
[edit] Uncertainty principle and observer effect
The uncertainty principle is often stated this way:
The measurement of position necessarily disturbs a particle's momentum, and vice versa
This makes the uncertainty principle a kind of observer effect.
This explanation is not incorrect, and was used by both Heisenberg and Bohr. But they were working within the philosophical framework of logical positivism. In this way of looking at the world, the true nature of a physical system, inasmuch as it exists, is defined by the answers to the best-possible measurements which can be made in principle. So when they made arguments about unavoidable disturbances in any conceivable measurement, it was obvious to them that this uncertainty was a property of the system, not of the devices.
Today, logical positivism has become unfashionable in many cases, so the explanation of the uncertainty principle in terms of observer effect can be misleading. For one, this explanation makes it seem to the non positivist that the disturbances are not a property of the particle, but a property of the measurement process— the particle secretly does have a definite position and a definite momentum, but the experimental devices we have are not good enough to find out what these are. This interpretation is not compatible with standard quantum mechanics. In quantum mechanics, states which have both definite position and definite momentum at the same time just don't exist.
This explanation is misleading in another way, because sometimes it is a failure to measure the particle that produces the disturbance. For example, if a perfect photographic film contains a small hole, and an incident photon is not observed, then its momentum becomes uncertain by a large amount. By not observing the photon, we discover indirectly that it went through the hole, revealing the photon's position.
The third way in which the explanation can be misleading is due to the nonlocal nature of a quantum state. Sometimes, two particles can be entangled, and then a distant measurement can be performed on one of the two. This measurement should not disturb the other particle in any classical sense, but it can sometimes reveal information about the distant particle. This restricts the possible values of position or momentum in strange ways.
Unlike the other examples, a distant measurement will never cause the overall distribution of either position or momentum to change. The distribution only changes if the results of the distant measurement are known. A secret distant measurement has no effect whatsoever on a particle's position or momentum distribution. But the distant measurement of momentum for instance will still reveal new information, which causes the total wavefunction to collapse. This will restrict the distribution of position and momentum, once that classical information has been revealed and transmitted.
For example If two photons are emitted in opposite directions from the decay of positronium, the momenta of the two photons are opposite. By measuring the momentum of one particle, the momentum of the other is determined, making its momentum distribution sharper, and leaving the position just as indeterminate. But unlike a local measurement, this process can never produce more position uncertainty than what was already there. It is only possible is to restrict the uncertainties in different ways, with different statistical properties, depending on what property of the distant particle you choose to measure. By restricting the uncertainty in p to be very small by a distant measurement, the remaining uncertainty in x stays large. (This example was actually the basis of Albert Einstein's important suggestion of the EPR paradox in 1935.)
This queer mechanism of quantum mechanics is the basis of quantum cryptography, where the measurement of a value on one of two entangled particles at one location forces, via the uncertainty principle, a property of a distant particle to become indeterminate and hence unmeasurable.
But Heisenberg did not focus on the mathematics of quantum mechanics, he was primarily concerned with establishing that the uncertainty is actually a property of the world — that it is in fact physically impossible to measure the position and momentum of a particle to a precision better than that allowed by quantum mechanics. To do this, he used physical arguments based on the existence of quanta, but not the full quantum mechanical formalism.
This was a surprising prediction of quantum mechanics, and not yet accepted. Many people would have considered it a flaw that there are no states of definite position and momentum. Heisenberg was trying to show this was not a bug, but a feature—a deep, surprising aspect of the universe. To do this, he could not just use the mathematical formalism, because it was the mathematical formalism itself that he was trying to justify.
[edit] Heisenberg's microscope
Heisenberg's gamma-ray microscope for locating an electron (shown in blue). The incoming gamma ray (shown in green) is scattered by the electron up into the microscope's aperture angle θ. The scattered gamma-ray is shown in red. Classical optics shows that the electron position can be resolved only up to an uncertainty Δx that depends on θ and the wavelength λ of the incoming light.
Main article: Heisenberg's microscope
One way in which Heisenberg originally argued for the uncertainty principle is by using an imaginary microscope as a measuring device.[3] He imagines an experimenter trying to measure the position and momentum of an electron by shooting a photon at it.
If the photon has a short wavelength, and therefore a large momentum, the position can be measured accurately. But the photon scatters in a random direction, transferring a large and uncertain amount of momentum to the electron. If the photon has a long wavelength and low momentum, the collision doesn't disturb the electron's momentum very much, but the scattering will reveal its position only vaguely.
If a large aperture is used for the microscope, the electron's location can be well resolved (see Rayleigh criterion); but by the principle of conservation of momentum, the transverse momentum of the incoming photon and hence the new momentum of the electron resolves poorly. If a small aperture is used, the accuracy of the two resolutions is the other way around.
The trade-offs imply that no matter what photon wavelength and aperture size are used, the product of the uncertainty in measured position and measured momentum is greater than or equal to a lower bound, which is up to a small numerical factor equal to Planck's constant.[5] Heisenberg did not care to formulate the uncertainty principle as an exact bound, and preferred to use it as a heuristic quantitative statement, correct up to small numerical factors.
[edit] Critical reactions
Main article: Einstein-Bohr debates
The Copenhagen interpretation of quantum mechanics and Heisenberg's Uncertainty Principle were in fact seen as twin targets by detractors who believed in an underlying determinism and realism. Within the Copenhagen interpretation of quantum mechanics, there is no fundamental reality the quantum state describes, just a prescription for calculating experimental results. There is no way to say what the state of a system fundamentally is, only what the result of observations might be.
Albert Einstein believed that randomness is a reflection of our ignorance of some fundamental property of reality, while Niels Bohr believed that the probability distributions are fundamental and irreducible, and depend on which measurements we choose to perform. Einstein and Bohr debated the uncertainty principle for many years.
[edit] Einstein's slit
The first of Einstein's thought experiments challenging the uncertainty principle went as follows:
Consider a particle passing through a slit of width d. The slit introduces an uncertainty in momentum of approximately h/d because the particle passes through the wall. But let us determine the momentum of the particle by measuring the recoil of the wall. In doing so, we find the momentum of the particle to arbitrary accuracy by conservation of momentum.
Bohr's response was that the wall is quantum mechanical as well, and that to measure the recoil to accuracy ΔP the momentum of the wall must be known to this accuracy before the particle passes through. This introduces an uncertainty in the position of the wall and therefore the position of the slit equal to h / ΔP, and if the wall's momentum is known precisely enough to measure the recoil, the slit's position is uncertain enough to disallow a position measurement.
A similar analysis with particles diffracting through multiple slits is given by Richard Feynman[6].
[edit] Einstein's box
Another of Einstein's thought experiments was designed to challenge the time/energy uncertainty principle. It is very similar to the slit experiment in space, except here the narrow window the particle passes through is in time:
Consider a box filled with light. The box has a shutter that a clock opens and quickly closes at a precise time, and some of the light escapes. We can set the clock so that the time that the energy escapes is known. To measure the amount of energy that leaves, Einstein proposed weighing the box just after the emission. The missing energy lessens the weight of the box. If the box is mounted on a scale, it is naively possible to adjust the parameters so that the uncertainty principle is violated.
Bohr spent a day considering this setup, but eventually realized that if the energy of the box is precisely known, the time the shutter opens at is uncertain. If the case, scale, and box are in a gravitational field then, in some cases, it is the uncertainty of the position of the clock in the gravitational field that alters the ticking rate. This can introduce the right amount of uncertainty. This was ironic, because it was Einstein himself who first discovered gravity's effect on clocks.
[edit] EPR measurements
Bohr was compelled to modify his understanding of the uncertainty principle after another thought experiment by Einstein. In 1935, Einstein, Podolski and Rosen (see EPR paradox) published an analysis of widely separated entangled particles. Measuring one particle, Einstein realized, would alter the probability distribution of the other, yet here the other particle could not possibly be disturbed. This example led Bohr to revise his understanding of the principle, concluding that the uncertainty was not caused by a direct interaction.[7]
But Einstein came to much more far-reaching conclusions from the same thought experiment. He believed as "natural basic assumption" that a complete description of reality would have to predict the results of experiments from "locally changing deterministic quantities", and therefore would have to include more information than the maximum possible allowed by the uncertainty principle.
In 1964 John Bell showed that this assumption can be falsified, since it would imply a certain inequality between the probabilities of different experiments. Experimental results confirm the predictions of quantum mechanics, ruling out Einstein's basic assumption that led him to the suggestion of his hidden variables. (Ironically this is one of the best examples for Karl Popper's philosophy of invalidation of a theory by falsification-experiments; i.e. here Einstein's "basic assumption" became falsified by experiments based on Bells inequalities; for the objections of Karl Popper against the Heisenberg inequality itself, see below.)
While it is possible to assume that quantum mechanical predictions are due to nonlocal hidden variables, and in fact David Bohm invented such a formulation, this is not a satisfactory resolution for the vast majority of physicists. The question of whether a random outcome is predetermined by a nonlocal theory can be philosophical, and potentially intractable. If the hidden variables are not constrained, they could just be a list of random digits that are used to produce the measurement outcomes. To make it sensible, the assumption of nonlocal hidden variables is sometimes augmented by a second assumption — that the size of the observable universe puts a limit on the computations that these variables can do. A nonlocal theory of this sort predicts that a quantum computer encounters fundamental obstacles when it tries to factor numbers of approximately 10,000 digits or more; an achievable task in quantum mechanics[8].
[edit] Popper's criticism
Karl Popper criticized Heisenberg's form of the uncertainty principle, that a measurement of position disturbs the momentum, based on the following observation: if a particle with definite momentum passes through a narrow slit, the diffracted wave has some amplitude to go in the original direction of motion. If the momentum of the particle is measured after it goes through the slit, there is always some probability, however small, that the momentum will be the same as it was before.
Popper thinks of these rare events as falsifications of the uncertainty principle in Heisenberg's original formulation. To preserve the principle, he concludes that Heisenberg's relation does not apply to individual particles or measurements, but only to many identically prepared particles, called ensembles. Popper's criticism applies to nearly all probabilistic theories, since a probabilistic statement requires many measurements to either verify or falsify.
Popper's criticism does not trouble physicists who subscribe to Copenhagen interpretation. Popper's presumption is that the measurement is revealing some preexisting information about the particle, the momentum, which the particle already possesses. According to Copenhagen interpretation the quantum mechanical description the wavefunction is not a reflection of ignorance about the values of some more fundamental quantities, it is the complete description of the state of the particle. In this philosophical view, Popper's example is not a falsification, since after the particle diffracts through the slit and before the momentum is measured, the wavefunction is changed so that the momentum is still as uncertain as the principle demands.
[edit] Refinements
[edit] Entropic uncertainty principle
Main article: Hirschman uncertainty
While formulating the many-worlds interpretation of quantum mechanics in 1957, Hugh Everett III discovered a much stronger formulation of the uncertainty principle[9]. In the inequality of standard deviations, some states, like the wavefunction
have a large standard deviation of position, but are actually a superposition of a small number of very narrow bumps. In this case, the momentum uncertainty is much larger than the standard deviation inequality would suggest. A better inequality uses the Shannon information content of the distribution, a measure of the number of bits learned when a random variable described by a probability distribution has a certain value.
The interpretation of I is that the number of bits of information an observer acquires when the value of x is given to accuracy ε is equal to Ix + log2(ε). The second part is just the number of bits past the decimal point, the first part is a logarithmic measure of the width of the distribution. For a uniform distribution of width Δx the information content is log2Δx. This quantity can be negative, which means that the distribution is narrower than one unit, so that learning the first few bits past the decimal point gives no information since they are not uncertain.
Taking the logarithm of Heisenberg's formulation of uncertainty in natural units.
but the lower bound is not precise.
Everett (and Hirschman[10]) conjectured that for all quantum states:
This was proven by Beckner in 1975[11].
[edit] Derivations
When linear operators A and B act on a function ψ(x), they don't always commute. A clear example is when operator B multiplies by x, while operator A takes the derivative with respect to x. Then
which in operator language means that
This example is important, because it is very close to the canonical commutation relation of quantum mechanics. There, the position operator multiplies the value of the wavefunction by x, while the corresponding momentum operator differentiates and multiplies by , so that:
It is the nonzero commutator that implies the uncertainty.
For any two operators A and B:
which is a statement of the Cauchy-Schwarz inequality for the inner product of the two vectors and . The expectation value of the product AB is greater than the magnitude of its imaginary part:
and putting the two inequalities together for Hermitian operators gives a form of the Robertson-Schrödinger relation:
and the uncertainty principle is a special case.
[edit] Physical interpretation
The inequality above acquires its physical interpretation:
where
is the mean of observable X in the state ψ and
is the standard deviation of observable X in the system state ψ.
By substituting for A and for B in the general operator norm inequality, since the imaginary part of the product, the commutator, is unaffected by the shift:
The big side of the inequality is the product of the norms of and , which in quantum mechanics are the standard deviations of A and B. The small side is the norm of the commutator, which for the position and momentum is just .
[edit] Matrix mechanics
In matrix mechanics, the commutator of the matrices X and P is always nonzero, it is a constant multiple of the identity matrix. This means that it is impossible for a state to have a definite values x for X and p for P, since then XP would be equal to the number xp and would equal PX.
The commutator of two matrices is unchanged when they are shifted by a constant multiple of the identity — for any two real numbers x and p
Given any quantum state ψ, define the number x
to be the expected value of the position, and
to be the expected value of the momentum. The quantities and are only nonzero to the extent that the position and momentum are uncertain, to the extent that the state contains some values of X and P that deviate from the mean. The expected value of the commutator
can only be nonzero if the deviations in X in the state times the deviations in P are large enough.
The size of the typical matrix elements can be estimated by summing the squares over the energy states :
and this is equal to the square of the deviation, matrix elements have a size approximately given by the deviation.
So, to produce the canonical commutation relations, the product of the deviations in any state has to be about .
This heuristic estimate can be made into a precise inequality using the Cauchy-Schwartz inequality, exactly as before. The inner product of the two vectors in parentheses:
is bounded above by the product of the lengths of each vector:
so, rigorously, for any state:
the real part of a matrix M is , so that the real part of the product of two Hermitian matrices is:
while the imaginary part is
The magnitude of is bigger than the magnitude of its imaginary part, which is the expected value of the imaginary part of the matrix:
Note that the uncertainty product is for the same reason bounded below by the expected value of the anticommutator, which adds a term to the uncertainty relation. The extra term is not as useful for the uncertainty of position and momentum, because it has zero expected value in a gaussian wavepacket, like the ground state of a harmonic oscillator. The anticommutator term is useful for bounding the uncertainty of spin operators though.
[edit] Wave mechanics
See also: Fourier uncertainty principle
In Schrödinger's wave mechanics, the quantum mechanical wavefunction contains information about both the position and the momentum of the particle. The position of the particle is where the wave is concentrated, while the momentum is the typical wavelength.
The wavelength of a localized wave cannot be determined very well. If the wave extends over a region of size L and the wavelength is approximately λ, the number of cycles in the region is approximately L / λ. The inverse of the wavelength can be changed by about 1 / L without changing the number of cycles in the region by a full unit, and this is approximately the uncertainty in the inverse of the wavelength,
This is an exact counterpart to a well known result in signal processing — the shorter a pulse in time, the less well defined the frequency. The width of a pulse in frequency space is inversely proportional to the width in time. It is a fundamental result in Fourier analysis, the narrower the peak of a function, the broader the Fourier transform.
Multiplying by h, and identifying ΔP = hΔ(1 / λ), and identifying ΔX = L.
The uncertainty Principle can be seen as a theorem in Fourier analysis: the standard deviation of the squared absolute value of a function, times the standard deviation of the squared absolute value of its Fourier transform, is at least 1/(16π2) (Folland and Sitaram, Theorem 1.1).
An instructive example is the (unnormalized) gaussian wave-function
The expectation value of X is zero by symmetry, and so the variance is found by averaging X2 over all positions with the weight ψ(x)2, careful to divide by the normalization factor.
The Fourier transform of the Gaussian is the wavefunction in k space, where k is the wavenumber and is related to the momentum by DeBroglie's relation :
The last integral does not depend on p, because there is a continuous change of variables which removes the dependence, and this deformation of the integration path in the complex plane does not pass through any singularities. So up to normalization, the answer is again a Gaussian.
The width of the distribution in k is found in the same way as before, and the answer just flips A to 1/A.
so that for this example
which shows that the uncertainty relation inequality is tight. There are wavefunctions that saturate the bound.
[edit] Symplectic geometry
This section requires expansion.
In mathematical terms, conjugate variables forms part of a symplectic basis, and the uncertainty principle corresponds to the symplectic form.
[edit] Robertson–Schrödinger relation
Given any two Hermitian operators A and B, and a system in the state ψ, there are probability distributions for the value of a measurement of A and B, with standard deviations ΔψA and ΔψB. Then
where [A,B] = AB - BA is the commutator of A and B, {A,B}= AB+BA is the anticommutator, and is the expectation value. This inequality is called the Robertson-Schrödinger relation, and includes the Heisenberg uncertainty principle as a special case. The inequality with the commutator term only was developed in 1930 by Howard Percy Robertson, and Erwin Schrödinger added the anticommutator term a little later.
[edit] Other uncertainty principles
The Robertson Schrödinger relation gives the uncertainty relation for any two observables that do not commute:
There is an uncertainty relation between the position and momentum of an object:
between the energy and position of a particle in a one-dimensional potential V(x):
between angular position and angular momentum of an object with small angular uncertainty:
between two orthogonal components of the total angular momentum operator of an object:
where i, j, k are distinct and Ji denotes angular momentum along the xi axis.
between the number of electrons in a superconductor and the phase of its Ginzburg-Landau order parameter[12][13]
[edit] Energy-time uncertainty principle
One well-known uncertainty relation is not an obvious consequence of the Robertson-Schrödinger relation: the energy-time uncertainty principle.
Since energy bears the same relation to time as momentum does to space in special relativity, it was clear to many early founders, Niels Bohr among them, that the following relation holds:
but it was not obvious what Δt is, because the time at which the particle has a given state is not an operator belonging to the particle, it is a parameter describing the evolution of the system. As Lev Landau once joked "To violate the time-energy uncertainty relation all I have to do is measure the energy very precisely and then look at my watch!"
Nevertheless, Einstein and Bohr understood the heuristic meaning of the principle. A state that only exists for a short time cannot have a definite energy. To have a definite energy, the frequency of the state must accurately be defined, and this requires the state to hang around for many cycles, the reciprocal of the required accuracy.
For example, in spectroscopy, excited states have a finite lifetime. By the time-energy uncertainty principle, they do not have a definite energy, and each time they decay the energy they release is slightly different. The average energy of the outgoing photon has a peak at the theoretical energy of the state, but the distribution has a finite width called the natural linewidth. Fast-decaying states have a broad linewidth, while slow decaying states have a narrow linewidth.
The broad linewidth of fast decaying states makes it difficult to accurately measure the energy of the state, and researchers have even used microwave cavities to slow down the decay-rate, to get sharper peaks[14]. The same linewidth effect also makes it difficult to measure the rest mass of fast decaying particles in particle physics. The faster the particle decays, the less certain is its mass.
One false formulation of the energy-time uncertainty principle says that measuring the energy of a quantum system to an accuracy ΔE requires a time interval Δt > h / ΔE. This formulation is similar to the one alluded to in Landau's joke, and was explicitly invalidated by Y. Aharonov and D. Bohm in 1961. The time Δt in the uncertainty relation is the time during which the system exists unperturbed, not the time during which the experimental equipment is turned on.
In 1936, Dirac offered a precise definition and derivation of the time-energy uncertainty relation, in a relativistic quantum theory of "events". In this formulation, particles followed a trajectory in space time, and each particle's trajectory was parametrized independently by a different proper time. The many-times formulation of quantum mechanics is mathematically equivalent to the standard formulations, but it was in a form more suited for relativistic generalization. It was the inspiration for Shin-Ichiro Tomonaga's covariant perturbation theory for quantum electrodynamics.
But a better-known, more widely-used formulation of the time-energy uncertainty principle was given only in 1945 by L. I. Mandelshtam and I. E. Tamm, as follows.[15] For a quantum system in a non-stationary state and an observable B represented by a self-adjoint operator , the following formula holds:
where ΔψE is the standard deviation of the energy operator in the state , ΔψB stands for the standard deviation of the operator and is the expectation value of in that state. Although, the second factor in the left-hand side has dimension of time, it is different from the time parameter that enters Schrödinger equation. It is a lifetime of the state with respect to the observable B. In other words, this is the time after which the expectation value changes appreciably.
[edit] Uncertainty theorems in harmonic analysis
In the context of harmonic analysis, the uncertainty principle implies that one cannot at the same time localize the value of a function and its Fourier transform; to wit, the following inequality holds
Other purely mathematical formulations of uncertainty exist between a function ƒ and its Fourier transform. A variety of such results can be found in (Havin & Jöricke 1994) or (Folland & Sitaram 1997); for a short survey, see (Sitaram 2001).
[edit] Benedicks's theorem
Benedicks's theorem (Benedicks 1985) intuitively says that the set of points where ƒ is non-zero and the set of points where is nonzero cannot both be small. Specifically, it is impossible for a function ƒ in L2(R) and its Fourier transform to both be supported on sets of finite Lebesgue measure. In signal processing, this result is well-known: a function cannot be both time limited and band limited.
[edit] Hardy's uncertainty principle
The mathematician G. H. Hardy (Hardy 1933) formulated the following uncertainty principle: it is not possible for ƒ and to both be "very rapidly decreasing." Specifically, if ƒ is in L2(R), then one has
unless ƒ = 0. Note that this result is sharp, since the Fourier transform of ƒ0(x) = e−πx2 is equal to e−πξ2: if e2π xξ is replaced in the integral above by ea xξ , for any a <>
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